Selectivity of Polyelectrolyte Membranes
نویسندگان
چکیده
منابع مشابه
Selectivity of Polyelectrolyte Membranes
The major factors contributing to the selectivity of charged synthetic membranes are discussed. Transport through porous polyelectrolyte membranes, containing water-filled interstices, can be predicted approximately from Donnan equilibria, representing the interaction between polyelectrolyte and counter-ions by "ion-binding". A simple relation between permselectivity and maximal salt rejection ...
متن کاملMethanol crossover and selectivity of nafion/heteropolyacid/montmorillonite nanocomposite proton exchange membranes for DMFC applications
In this work, we prepared the nafion/montmorillonite/heteropolyacid nanocomposite membranes for direct methanol fuel cells (DMFCs). The analyses such as X-ray diffraction (XRD), Fourier transform infrared (FTIR), and scanning electron microscopy (SEM) were conducted to characterize the filler dispersion and membrane structure in prepared nanocomposite membranes. XRD patterns of nafion-CsPW-MMT ...
متن کاملExtrinsic Cation Selectivity of 2D Membranes
From a systematic study of the concentration driven diffusion of positive and negative ions across porous 2D membranes of graphene and hexagonal boron nitride (h-BN), we prove their cation selectivity. Using the current-voltage characteristics of graphene and h-BN monolayers separating reservoirs of different salt concentrations, we calculate the reversal potential as a measure of selectivity. ...
متن کاملSelectivity of Direct Methanol Fuel Cell Membranes
Sulfonic acid-functionalized polymer electrolyte membranes alternative to Nafion(®) were developed. These were hydrocarbon systems, such as blend sulfonated polyetheretherketone (s-PEEK), new generation perfluorosulfonic acid (PFSA) systems, and composite zirconium phosphate-PFSA polymers. The membranes varied in terms of composition, equivalent weight, thickness, and filler and were investigat...
متن کاملProtein Separation via Polyelectrolyte Coacervation: Selectivity and Efficiency
Selective phase separation with polyelectrolytes can be used to separate a mixture of proteins. The efficiency of separation was examined using the cationic polyelectrolyte poly(diallyldimethylammonium chloride) and the model proteins bovine serum albumin, â-lactoglobulin, γ-globulin, and ribonuclease A. The coacervation yield for individual proteins and the degree of separation, for selected p...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Pure and Applied Chemistry
سال: 1976
ISSN: 1365-3075,0033-4545
DOI: 10.1351/pac197646020187